PEROXIDE FORMING COMPOUNDS

CLASS A

Chemicals that can spontaneously form peroxides under normal storage conditions without being exposed to air. These are the most dangerous type of peroxide formers because they have the highest risk of forming explosive peroxides.

 

 

 

CLASS B

Chemicals that can spontaneously form peroxides by prolonged contact with oxygen or with being exposed to air to develop dangerous levels of peroxides. These chemicals are commonly hazardous when concentrated, distilled, or evaporated, as the peroxide crystals that may form are highly explosive.

CLASS C

Chemicals that can readily form highly explosive polymeric peroxides when exposed to air, light, or heat. These materials are particularly hazardous due to their tendency to undergo dangerous polymerization reactions initiated or exacerbated by peroxide formation.

 

Examples:

  • Butadiene

  • Isopropyl Ether

  • Divinyl Ether

Examples:

  • Diethyl Ether

  • Tetrahydrofuran (THF)

  • Acetaldehyde

Examples:

  • Acrylic Acid

  • Chlorobutadiene

  • Styrene

COMMON PEROXIDE FORMING FUNCTIONAL GROUPS

    
 ether
chemical makeup of ether


aldehyde

chemical makeup of aldehyde

 

ketone

chemical makeup of ketone

 

alkene

chemical makeup of alkene

ketal

acetal and ketal

Common Solvents:

amide

urethane formula structure

 

amide chemical formula

 

Common Solvents:

dienes

dienes chemical formula